Course title
3M8201001
Organic Reactions I

 kitagawa osamu Click to show questionnaire result at 2018
Course content
In undergraduate course, we learned various organic reactions on the basis of Electronic Theory of Organic Chemistry. This theory is very useful to understand polar reactions, while this is not available in non-polar reactions such as peri-cyclic reaction. This course is explanation of non-polar reactions on the basis of Molecular Orbital Theory. In addition, aromaticity, anomeric effect and gauche effect will be explained by using MO Theory.
Purpose of class
Construction of π-molecular orbitals in various conjugated π-electron compounds, and understanding of various chemical reactions and structural property of organic compounds through MO theory
Goals and objectives
  1. Construction of π-molecular orbitals in various conjugated π-electron compounds．
  2. Understanding of selectivity and reactivity in peri-cyclic reactions by Woodword-Hoffmann rule.
  3. Understanding of chemical characterization in various conjugated π-electron compounds by Molecular Orbital Theory．
  4. Understanding of polar reaction by Molecular Orbital Theory
  5. Understanding of anomer and gauche effects by Molecular Orbital Theory
Language
Japanese
Class schedule

 Class schedule HW assignments (Including preparation and review of the class.) Amount of Time Required
1． Electronic Theory of Organic Chemistry and Molecular Orbital Theory Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
2． Atomic orbital and molecular orbital Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
3． Construction of molecular orbital (sigma-bond and pi-bond) Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
4． Construction of molecular orbital (conjugated pi-orbital) Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
5． Frontier Orbital Theory Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
6． Woodward-Hoffmann rule Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
7． Peri-cyclic reaction Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
8． Peri-cyclic cycloaddition reaction Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
9． Diels-Alder reaction Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
10． Chemical characterization of conjugated polyene compounds Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
11． Aromaticity Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
12． Anti-aromaticity Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
13． Explanation of polar reaction on the basis of Molecular Orbital Theory Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
14． Anomer effect and hyper conjugation Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
Total. - - 2800minutes
Relationship between 'Goals and Objectives' and 'Course Outcomes'

 report Total.
1. 20% 20%
2. 20% 20%
3. 20% 20%
4. 20% 20%
5. 20% 20%
Total. 100% -
Evaluation method and criteria
The credit requires over 60% of total scores on the reports of which include the topics of goals and the objectives.
Textbooks and reference materials
Prints will be distributed.
Prerequisites
no need
Office hours and How to contact professors for questions
  • Wednesday pm 2:00 - pm 4:00
Relation to the environment
Non-environment-related course
Regionally-oriented
Non-regionally-oriented course
Development of social and professional independence
  • Non-social and professional independence development course
Active-learning course
About half of the classes are interactive
Course by professor with work experience
Work experience Work experience and relevance to the course content if applicatable
N/A N/A
Last modified : Thu Mar 21 15:21:51 JST 2019