Course title
D02305003
Synthetic Polymer Chemistry

naga naofumi Click to show questionnaire result at 2018
Course description
Large amount of polymer metrials are widely used nowadays. The polymer is one of the indispensable mataterials for our life. High peformance and highly functinalyzed the polymer materials should be nessary for application in high technology industry. Furthermore, enviomental harmonization of the polymer materials should be required. In this recture, we study about basics of polymer synthesis and features of various polymerization methods, which should be usable for development of new polymer materials.
Purpose of class
Studying about basic reactions of polymer synthesis: radical polymerization, cationic polymerization, anionic polymerization, coordination polymerization, condensation polymerization, addition polymerization, addition-condensation polymerization, ring-opening polymerization, group transfer polymerization.
Studying about basic polymer reactions: degradation, functinalyzation.
Goals and objectives
  1. Learning about chian polymerizations (Lectures 1-6)
  2. Learning about sequential polymerizations (Lectures 8 & 9)
  3. Learning about other polymerizations (Lectures 10 & 11)
  4. Learning about chemcal reactions of polymers (Lecture 12)
  5. Learning about bio polymers (Lecture 13)
Language
Japanese
Class schedule

Class schedule HW assignments (Including preparation and review of the class.) Amount of Time Required
1. Radical polymerization (1):
Initiators for radical polymerization, Basci reactions of radical polymerization
Look over Section 2 P36〜P49、P59〜P60 of the text book. Reconfirmation of the exercise in Lecture 1. 200minutes
2. Radical polymerization (2):
Kinetic study of radical polymerization
Look over Section 2 P49〜P50、P59〜P60 of the text book. Reconfirmation of the exercise in Lecture 2. 200minutes
3. Radical polymerization (3):
Radical copolymerization, monomer reaction ratio
Look over Section 2 P51〜P56 of the text book. Reconfirmation of the exercise in Lecture 3. 200minutes
4. Ionic polymerization (1) Cationic polymerization:
Features of cationic polymerization, Initiators and monomers, Basci reactions of cationic polymerization
Look over Section 2 P69〜P74 of the text book. Reconfirmation of the exercise in Lecture 4. 200minutes
5. Ionic polymerization (2) Anionic polymerization:
Features of anionic polymerization, Initiators and monomers, Basci reactions of anionic polymerization
Look over Section 2 P64〜P69 of the text book. Reconfirmation of the exercise in Lecture 5. 200minutes
6. Coordination polymerization:
Ziegler-Natta catalyst, Metallocene catalyst, Stereo specfic polymerization, Methathesis polymerization
Look over Section 2 P76〜P80 of the text book. Reconfirmation of the exercise in Lecture 6. 200minutes
7. Midterm examination & explnation Review the contents of Lectures 1-6. Reconfirmation of answers of the midterm examination. 200minutes
8. Condensation polymerization (1):
Features of condensation polymerization, Kinetics
Look over Section 2 P20, 29〜P33 of the text book. Reconfirmation of answers of the midterm examination. 200minutes
9. Condensation polymerization (2):
Polymers synthesized by condensation polymerization
Look over Section 2 P22〜P28, P33〜P36 of the text book. Reconfirmation of the exercise in Lecture 9. 190minutes
10. Other polymerization reactions (1):
Addition polymerization, Addition-condensation polymerization
Look over Section 2 P80〜P85 of the text book. Reconfirmation of the exercise in Lecture 10. 200minutes
11. Other polymerization reactions (2):
Ring opening polymerization, Group transfer polymerization
Look over Section 2 P74〜P75 of the text book. Reconfirmation of the exercise in Lecture 11. 200minutes
12. Polymer reaction
Functionalyzation of polymer, Degradation of polymer
Look over Section 2 P57, P86〜91 of the text book. Reconfirmation of the exercise in Lecture 12. 200minutes
13. Bio polymer Look over Section 2 P248〜P255 of the text book. Reconfirmation of the exercise in Lecture 13. 200minutes
14. Term examination & explnation Review the contents of Lectures 9-13. Reconfirmation of answers of the term examination. 200minutes
Total. - - 2790minutes
Relationship between 'Goals and Objectives' and 'Course Outcomes'

Midterm examination Term examination Total.
1. 50% 50%
2. 20% 20%
3. 10% 10%
4. 10% 10%
5. 10% 10%
Total. 50% 50% -
Evaluation method and criteria
Objectives 1 and 2 are evaluated by the midterm examination. Objectives 3, 4 and 5 are evaluated by the term examination.
Passing grade is more than 60% (exercise level) of tatal socres (midtermexamination (50%) + term examination (50%). You have the exercise of previlus lecture at the bigginig of evely lecture to chekc your attendance. Morethan 2/3 of attendances should be nessary to have the term examination.
Textbooks and reference materials
Shin-Kobunshi Kagaku Jhoron (Kagaku Dojin, Higashimura et al.)
Prerequisites
I recommend you to have studied about organic chemistry.
Office hours and How to contact professors for questions
  • 9:00-19:30, make an appointment via e-mail in advance.
Relation to the environment
Non-environment-related course
Regionally-oriented
Non-regionally-oriented course
Development of social and professional independence
  • Course that cultivates an ability for utilizing knowledge
Active-learning course
N/A
Course by professor with work experience
Work experience Work experience and relevance to the course content if applicatable
Applicatable Development of olefin-based polymers
Last modified : Thu Mar 21 14:30:03 JST 2019