Based on fundamental knowledges obtained in Inorganic Chemistry 1 and 2, this lecture will provide introduction to advanced
research fields of inorganic chemistry. Special focus will be put on metal complexes, solid state materials, and electrochemical
materials. About these topics, important inorganic phenomena such as crystal structures, bonding, and chemical reactions will
be discussed. In addition, overview of recent researches and industrial applications will be given.
This lecture aims to make students recognize importance of inorganic chemistry in advanced research and industrial applications
by introducing research and development of metal complexes, solid state materials, and electrochemical materials. The lecture
also aims to enhance knowledge about inorganic chemistry by studying important inorganic phenomena such as structures, bonding
mechanisms, and chemical reactions.
- Students will recognize importance of inorganic chemistry in advanced research and industrial applications by studying inorganic chemistry and devices of metal complexes, solid state materials, and electrochemical materials.
- Students will understand bonding, electronic structures, and chemical reactions of metal complexes.
- Students will understand crystal structures and electronic structures of solid state materials.
- Students will understand relationship between Gibbs free energy and electrochemical potential. Also, students will understand standard electrode potential.
| Class schedule | HW assignments (Including preparation and review of the class.) | Amount of Time Required | |
|---|---|---|---|
| 1. | Inorganic chemistry of metal complex As a basis of metal complex, concept of coordination chemistry, nomenclature, ligands, and molecular structures will be introduced. |
Preparation and review of coordination chemistry. | 120minutes |
| 2. | Electronic structure and properties of metal complex Based on crystal field theory and ligand field theory, electronic structure of metal complexes will be explained. In addition, interesting properties derived from the electronic structures will be introduced. |
Preparation and review of metal complexes. | 120minutes |
| 3. | Reaction mechanism of metal complex Three important reaction mechanisms observed in displacement reactions of metal complexes will be discussed. |
Preparation and review of reaction mechanisms of metal complexes. | 120minutes |
| 4. | Organometallic compound Types, bonding, and chemical reactions of organometallic compounds will be discussed. |
Preparation and review of organometallic compounds. | 120minutes |
| 5. | Catalysis of metal complex As an important example of applications of metal complexes, catalysis will be introduced. |
Preparation and review of catalysis of metal complex. | 120minutes |
| 6. | Life activity and metal complex Significance of metal complexes in life activities will be introduced. |
Preparation and review of role of metal complexes in life activity. | 120minutes |
| 7. | Crystal structure of solid state material Crystal structures of solid state materials will be discussed. |
Preparation and review of crystal structures of solid state materials. | 120minutes |
| 8. | Electronic structures of solid state material Difference in electronic structures of metals, insulators, and semiconductors will be discussed. Then, as a example of important applications of solid state materials, semiconducting devices will be introduced. |
Preparation and review of electronic structures of solid state materials. | 120minutes |
| 9. | Defects of solid state material and diffusion Concepts of defects and their role on atomic diffusion in solid state materials will be studied. Further, as an example of diffusion-driven functionalities, ionic conduction will be introduced. |
Preparation and review of defects of solid state material and diffusion. | 120minutes |
| 10. | Applications of solid state material Other applications will be overviewed to emphasize importance of solid state materials in research and industrial activities of inorganic chemistry. |
Preparation and review of applications of solid state materials. | 120minutes |
| 11. | Energy and electric potential Relationships between Gibbs free energy and electric potential will e discussed. |
Preparation and review of Gibbs free energy and electric potential. | 120minutes |
| 12. | Standard electrode potential and electromotive force of battery Standard electrode potential will be introduced. In addition, relationship between standard electrode potential and electromotive force will be discussed. |
Preparation and review of Standard electrode potential and electromotive force of battery. | 120minutes |
| 13. | Lithium ion battery As an example of electrochemical applications, lithium ion batteries will be introduced. Their structure, operating principles, and recent researches will be discussed. |
Preparation and review of lithium ion batteries. | 120minutes |
| 14. | Final exam Final exam will evaluate fundamental knowledges of students about inorganic chemistry of metal complexes, solid state materials, and electrochemical materials. The exam also evaluate students’ ability to explain advanced inorganic phenomena and operating principles of application devices based on the fundamental knowledges. |
Review of slides distributed in lectures from #7 to #13 before the exam. | 120minutes |
| Total. | - | - | 1680minutes |
| Report | Final exma | Quiz | Total. | |
|---|---|---|---|---|
| 1. | 20% | 20% | 5% | 45% |
| 2. | 20% | 0% | 5% | 25% |
| 3. | 0% | 10% | 5% | 15% |
| 4. | 0% | 10% | 5% | 15% |
| Total. | 40% | 40% | 20% | - |
小テスト（20％）、レポート（40％）、期末試験（40％）。レポートの範囲は錯体化学全般（第1回から第6回までの講義に対応）。期末試験の範囲は固体化学および電気化学（第7回から第13回までの講義に対応）。総合得点率60％以上を合格とする。小テストは毎授業ごとに2回程度実施する。
Decision to pass or fail will be made by quizzes, a report, and a final exam. Students who take total score of more than 60% can take a credit. Topics of Report will be inorganic chemistry of metal complexes introduced in lectures from #1 to #6. Topics of final exam will be inorganic chemistry of solid state materials and electrochemical materials introduced in lectures from #7 to #13. Quizzes will be set about twice in a single lecture.
Decision to pass or fail will be made by quizzes, a report, and a final exam. Students who take total score of more than 60% can take a credit. Topics of Report will be inorganic chemistry of metal complexes introduced in lectures from #1 to #6. Topics of final exam will be inorganic chemistry of solid state materials and electrochemical materials introduced in lectures from #7 to #13. Quizzes will be set about twice in a single lecture.
【Reference】
"Inorganic Chemistry" Shriver & Atkins Oxford Univ Pr
「電子移動の化学－電気化学入門」 渡辺正、中林誠一郎著（朝倉書店）
「親しむ電子物性」 志村史夫著（朝倉書店）
「セラミック材料学」 佐久間健人著（海文堂）
「固体の高イオン伝導」 齋藤安俊、丸山俊夫著（内田老鶴圃）
「リチウムイオン電池の科学」 工藤徹一、日比野光宏、本間格著（内田老鶴圃）
"Inorganic Chemistry" Shriver & Atkins Oxford Univ Pr
「電子移動の化学－電気化学入門」 渡辺正、中林誠一郎著（朝倉書店）
「親しむ電子物性」 志村史夫著（朝倉書店）
「セラミック材料学」 佐久間健人著（海文堂）
「固体の高イオン伝導」 齋藤安俊、丸山俊夫著（内田老鶴圃）
「リチウムイオン電池の科学」 工藤徹一、日比野光宏、本間格著（内田老鶴圃）
- Students can ask questions by e-mail at anytime during this term.
- Course that cultivates an ability for utilizing knowledge
| Work experience | Work experience and relevance to the course content if applicatable |
|---|---|
| N/A | N/A |
Last modified : Thu Sep 10 04:03:47 JST 2020