Course title
3M8201001
Organic Reactions

 KITAGAWA Osamu Click to show questionnaire result at 2019
Course content
In undergraduate course, we learned various organic reactions on the basis of Electronic Theory of Organic Chemistry. This theory is very useful to understand polar reactions, while this is not available in non-polar reactions such as peri-cyclic reaction. This course is explanation of non-polar reactions on the basis of Molecular Orbital Theory. In addition, aromaticity, anomeric effect and gauche effect will be explained by using MO Theory.
Purpose of class
Construction of π-molecular orbitals in various conjugated π-electron compounds, and understanding of various chemical reactions and structural property of organic compounds through MO theory
Goals and objectives
  1. Construction of π-molecular orbitals in various conjugated π-electron compounds．
  2. Understanding of selectivity and reactivity in peri-cyclic reactions by Woodword-Hoffmann rule.
  3. Understanding of chemical characterization in various conjugated π-electron compounds by Molecular Orbital Theory．
  4. Understanding of polar reaction by Molecular Orbital Theory
  5. Understanding of anomer and gauche effects by Molecular Orbital Theory
Relationship between 'Goals and Objectives' and 'Course Outcomes'

 report Total.
1. 20% 20%
2. 20% 20%
3. 20% 20%
4. 20% 20%
5. 20% 20%
Total. 100% -
Language
Japanese
Class schedule

 Class schedule HW assignments (Including preparation and review of the class.) Amount of Time Required
1． Electronic Theory of Organic Chemistry and Molecular Orbital Theory Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
2． Construction of molecular orbital (sigma-bond and pi-bond) Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
3． Consideration of peri-cyclic ring-closing reaction based on Frontier Orbital Theory and Woodward-Hoffmann rule Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
4． Consideration of peri-cyclic ring-opening reaction and cycloaddition reaction based on Woodward-Hoffmann rule Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
5． Consideration of Diels-Alder reaction based on Frontier Orbital Theory Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
6． Consideration of polar reaction based on Molecular Orbital Theory Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
7． Consideration of conjugated pai-compounds based on Molecular Orbital Theory Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
8． Consideration of aromaticity and anti-aromaticity based on Molecular Orbital Theory Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
9． Conformational analysis based on Molecular Orbital Theory Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
10． Molecular Orbital Theory and transition metal catalyzed reactions (Suzuki-Miyaura cross coupling and Buchwald-Hartwig amination) Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
11． Molecular Orbital Theory and chiral organocatalyst Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
12． Molecular Orbital Theory and natural product synthesis Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
13． Molecular Orbital Theory and chirality Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
14． Advanced lecture on Molecular Orbital Theory Prints for preparation and review of the class will be distributed. Reading of these prints. 200minutes
Total. - - 2800minutes
Evaluation method and criteria
The credit requires over 60% of total scores on the reports of which include the topics of goals and the objectives.
Feedback on exams, assignments, etc.
ways of feedback specific contents about "Other"
Feedback in the class
Textbooks and reference materials
Prints will be distributed.
Prerequisites
no need
Office hours and How to contact professors for questions
  • Monday 9:00 am-12:00 am
Regionally-oriented
Non-regionally-oriented course
Development of social and professional independence
  • Non-social and professional independence development course
Active-learning course
About half of the classes are interactive
Course by professor with work experience
Work experience Work experience and relevance to the course content if applicable
N/A N/A
Education related SDGs:the Sustainable Development Goals
  • 4.QUALITY EDUCATION
Last modified : Tue Apr 01 04:06:59 JST 2025