Course title
D00050001
Analytical Chemistry

SEGAWA Hiroki
Course description
The primary aim of this course for students is to understand basic concepts on reactions in solutions, various types of chemical equilibrium, and application of them to analytical chemistry.
Purpose of class
The primary aim of this course for students is to understand basic concepts on reactions in solutions, various types of chemical equilibrium, and application of them to analytical chemistry.
Goals and objectives
  1. Students can calculate concentrations of solutions, ionic strength and activity of solutes.
  2. Students can calculate pH in acidic and basic solutions including buffer solutions.
  3. Students can calculate chemical equilibrium of metal complexes in solutions based on formation constants.
  4. Students can calculate solubility of slightly soluble salts based on solubility products.
Relationship between 'Goals and Objectives' and 'Course Outcomes'

midterm examination final examination Total.
1. 15% 15%
2. 35% 35%
3. 25% 25%
4. 25% 25%
Total. 50% 50% -
Evaluation method and criteria
Achievement of Goals and Objectives 1 and 2 will be evaluated through a midterm examination. Achievement of Goals and Objectives 3 and 4 will be evaluated through a final examination.
A maximum score of midterm examination is 40 points, and that of final examination is 60 points. The final evaluation is based on the cumulative score of midterm and final examinations. A minimum of 60 points is required to pass this course.
Language
Japanese
Class schedule

Class schedule HW assignments (Including preparation and review of the class.) Amount of Time Required
1. solution concentrations 1:
- mol, gram equivalent, molarity, normality
read the relevant sections of the distributed materials 200minutes
2. solution concentrations 2:
- conversion of solution concentrations (from % concentration to molarity and normality)
- dilution of concentrated solutions
- neutralization titration, pH
read the relevant sections of the distributed materials 200minutes
3. solution concentrations 3:
- weight percent, volume percent, ppm, ppb, ppt
- activity, ionic strength calculation
- pH calculation of solutions containing strong acid or base
read the relevant sections of the distributed materials 200minutes
4. acid-base equilibrium 1:
- concept of acid and base
- chemical equilibrium in solutions
read the relevant sections of the distributed materials 200minutes
5. acid-base equilibrium 2:
- pH calculation of solutions containing weak acid or case salt
- pH calculation of buffer solutions
read the relevant sections of the distributed materials 200minutes
6. acid-base equilibrium 3:
- chemical forms of polybasic acid
- neutralization titration and detection methods
read the relevant sections of the distributed materials 200minutes
7. acid-base equilibrium 4:
- summary of acid-base equilibrium and exercises
read the relevant sections of the distributed materials 200minutes
8. midterm examination
- scope of midterm examination is 1-7 above
- explanation on the examination will be provided after it is completed.
review the contents of lectures included in the scope of a midterm examination 400minutes
9. complex formation reaction 1:
- chelate compounds, monodentate and multidentate ligands, chelate formation
- stepwise formation constants, overall formation constants
read the relevant sections of the distributed materials 200minutes
10. complex formation reaction 2:
- speciation of metal complex ion, absolute formation constants, effective formation constants
- effect of pH in EDTA chelate formation
read the relevant sections of the distributed materials 200minutes
11. complex formation reaction 3:
- calculation of theoretical chelatometric titration curves for metal ions
read the relevant sections of the distributed materials 200minutes
12. precipitation equilibrium 1:
- dissolution of slightly soluble salts and solubility product
read the relevant sections of the distributed materials 200minutes
13. precipitation equilibrium 2:
- factors impacting on dissolution of slightly soluble salts
- calculation of precipitation titration curves
read the relevant sections of the distributed materials 400minutes
14. final examination
- scope of a final examination is 9-13 above
- explanation on the examination will be provided after it is completed.
review the contents of lectures included in the scope of a midterm examination 400minutes
15. *
Total. - - 3400minutes
Feedback on exams, assignments, etc.
ways of feedback specific contents about "Other"
授業内と授業外でフィードバックを行います。
Textbooks and reference materials
Textbook:「基礎 分析化学」宗林由樹、向井 浩共著/サイエンス社 and distributed reference materials (Japanese)
Exercise book:「基礎分析化学演習」菅原正雄著/三共出版 (Japanese)
Prerequisites
Students should review the contents learned in chemistry classes in high schools.
Office hours and How to contact professors for questions
  • Please ask the professor within and outside a lecture
  • Office hour: Tuesday, 13:20-16:50(please make an appointment)
Regionally-oriented
Non-regionally-oriented course
Development of social and professional independence
  • Course that cultivates an ability for utilizing knowledge
  • Course that cultivates a basic self-management skills
Active-learning course
N/A
Course by professor with work experience
Work experience Work experience and relevance to the course content if applicable
Applicable The professor has experience in application of analytical chemistry to forensic discrimination in the former affiliation.
Education related SDGs:the Sustainable Development Goals
  • 3.GOOD HEALTH AND WELL-BEING
  • 16.PEACE, JUSTICE AND STRONG INSTITUTIONS
Last modified : Mon Mar 31 04:03:34 JST 2025